زیرکونیوم کلراید 808913 مرک

Description
Catalogue Number	808913
Synonyms	Zirconium tetrachloride
Description	Zirconium(IV) chloride

Product Information
CAS number	10026-11-6
EC number	233-058-2
Hill Formula	Cl₄Zr
Chemical formula	ZrCl₄
Molar Mass	233.04 g/mol
HS Code	2827 39 85

Applications
Application	Zirconium(IV) chloride anhydrous, for synthesis. CAS 10026-11-6, EC Number 233-058-2, chemical formula ZrCl₄.

Physicochemical Information
Density	2.80 g/cm3 (15 °C)
Melting Point	437 °C
pH value	<1 (H₂O, 20 °C) (saturated aqueous solution)
Vapor pressure	1.3 hPa (190 °C)
Bulk density	1200 kg/m3

Toxicological Information
LD 50 oral	LD50 Rat 1688 mg/kg

Safety Information according to GHS
Hazard Pictogram(s)
Hazard Statement(s)	H302: Harmful if swallowed. H314: Causes severe skin burns and eye damage. EUH014: Reacts violently with water.
Precautionary Statement(s)	P280: Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P310: IF exposed or concerned: immediately call a POISON CENTER or doctor/ physician.
Signal Word	Danger
RTECS	ZH7175000
Storage class	8B Non-combustible, corrosive hazardous materials
WGK	WGK 1 slightly water endangering
Disposal	24 Liquid inorganic halides and hydrolysis-sensitive reagents can be carefully stirred dropwise into ice-cool 10% sodium hydroxide solution (Cat. No. 105587) (caution: caustic gases!); container D or E.

Safety Information
Hazard Symbols	Corrosive
Categories of danger	harmful, corrosive
R Phrase	R 14-22-34 Reacts violently with water.Harmful if swallowed.Causes burns.
S Phrase	S 8-26-36/37/39-45 Keep container dry.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

Storage and Shipping Information
Storage	Store below +30°C.

Transport Information
Declaration (railroad and road) ADR, RID	UN 2503 , 8, III
Declaration (transport by air) IATA-DGR	UN 2503 , 8, III
Declaration (transport by sea) IMDG-Code	UN 2503 , 8, III, Segregation Group: 1 (Acids)

Specifications
Assay (argentometric)	≥ 98.0 %
Hafnium (Hf)	≤ 40 ppm
Identity (ICP-OES)	passes test