آنیلین 101261 مرک

Description
Catalogue Number	101261
Synonyms	Aminobenzene, Phenylamine, Benzenamine
Overview	EMSURE® grade solvents are suitable for a broad spectrum of classical lab applications, and are frequently used in regulated and highly demanding lab applications. EMSURE® provides worldwide best and most extensive product specifications. We declare our EMSURE® range to be in compliance with the ACS, with the reagent part of the European Pharmacopoeia (Reag. Ph Eur) and also with the ISO standards.

Product Information
CAS number	62-53-3
EC index number	612-008-00-7
EC number	200-539-3
Hill Formula	C₆H₇N
Chemical formula	C₆H₅NH₂
Molar Mass	93.13 g/mol
HS Code	2921 41 00
Structure formula Image

Applications
Application	Aniline for analysis EMSURE®. CAS No. 62-53-3, EC Number 200-539-3.

Physicochemical Information
Boiling point	184 °C (1013 hPa)
Density	1.02 g/cm3 (20 °C)
Explosion limit	1.2 - 11 %(V)
Flash point	76 °C
Ignition temperature	540 °C
Melting Point	-6.2 °C
pH value	8.8 (36 g/l, H₂O, 20 °C)
Vapor pressure	0.5 hPa (20 °C)
Solubility	36 g/l

Toxicological Information
LD 50 dermal	LD50 Rabbit 840 mg/kg

Safety Information according to GHS
Hazard Pictogram(s)
Hazard Statement(s)	H301 + H311 + H331: Toxic if swallowed, in contact with skin or if inhaled. H317: May cause an allergic skin reaction. H318: Causes serious eye damage. H341: Suspected of causing genetic defects. H351: Suspected of causing cancer. H372: Causes damage to organs through prolonged or repeated exposure. H400: Very toxic to aquatic life.
Precautionary Statement(s)	P273: Avoid release to the environment. P280: Wear protective gloves. P280: Wear eye protection. P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P310: IF exposed or concerned: immediately call a POISON CENTER or doctor/ physician.
Storage class	6.1A Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK	WGK 2 water endangering
Disposal	9 Carcinogenic compounds and flammable compounds labelled "Highly toxic" or "Toxic": container F. Alkyl sulfates are carcinogenic; Take particular care to avoid inhalation and skin contact. To neutralize alkyl sulfates, add dropwise (from a dropping funnel) to concentrated ice-cool Ammonia solution (Cat.No. 105426) with vigorous stirring. Before placing in container D, check the pH with pH Universal indicator strips (Cat.No. 109535).

Safety Information
Hazard Symbols	Dangerous for the environment Toxic
Categories of danger	toxic, carcinogenic, irritant, sensitizing, mutagenic, dangerous for the environment
R Phrase	R 23/24/25-40-41-43-48/23/24/25-68-50 Toxic by inhalation, in contact with skin and if swallowed.Limited evidence of a carcinogenic effect.Risk of serious damage to eyes.May cause sensitisation by skin contact.Toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed.Possible risk of irreversible effects.Very toxic to aquatic organisms.
S Phrase	S 26-27-36/37/39-45-46-61-63 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Take off immediately all contaminated clothing.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).If swallowed, seek medical advice immediately and show this container or label.Avoid release to the environment. Refer to special instructions/ Safety data sheets.In case of accident by inhalation: remove casualty to fresh air and keep at rest.

Storage and Shipping Information
Storage	Store at +5°C to +30°C.

Transport Information
Declaration (railroad and road) ADR, RID	UN 1547 , 6.1, II
Declaration (transport by air) IATA-DGR	UN 1547 , 6.1, II
Declaration (transport by sea) IMDG-Code	UN 1547 , 6.1, II, Marine Pollutant: P

Specifications
Purity (GC)	≥ 99.5 %
Identity (IR)	conforms
Nitrobenzene (GC)	≤ 0.003 %
Sulfated ash	≤ 0.005 %
Water	≤ 0.1 %